ECTFE VS ETFE

So What's The Practical Deference? 

There is a lot of buzz in the plastics Semiconductor world about fluoropolymers, given the concerns surrounding the viability of the supply chain to service the anticipated demand. Further complicating the situation are the PFAS potential regulations and the void that will be caused by the exiting of the business by 3M. The fact is that fluoropolymers provide unique properties that cannot be easily replaced. They are inert, pure, and inherently flame-resistant, to name a few. As multiple industries rely on fluoropolymers, knowing where materials can be interchanged or optimized for specific applications becomes important.

ECTFE (Halar®) is a polymer manufactured by Solvay. Ethylene chlorotrifluoroethylene is a copolymer of ethylene and chlorotrifluoroethylene. ECTFE is a melt-processable, semi-crystalline white, semi-opaque thermoplastic with very good chemical resistance and barrier properties. ECTFE is a logical step up from PVDF in terms of chemical resistance while providing similar mechanical properties to PVDF and greatly enhanced mechanical properties compared to PTFE and PFA.

ETFE (Tefzel®) is a partially fluorinated copolymer of ethylene and trifluoroethylene (TFE). This chemical modification provides significantly higher strength relative to PTFE or PFA. It is less flexible than PTFE but has superior impact strength and abrasion resistance. Compared to ECTFE, the fully fluorinated TFE group allows for superior chemical resistance, while the partially chlorinated group in ECTFE enhances the mechanical properties. ETFE is a "tweener" when you need better mechanical properties than PFA or PTFE; however, when you need the nearly bullet-proof chemical resistance of PTFE and PFA.

  PVDF  PTFE (virgin) ETFE ECTFE  PFA PCTFE

Tensile Strength (ASTM D638, psi)

6,300

3,600

6,100

7,900

4,000

7,830

Tensile Modulus (ASTM D638, psi)

290,000

80,000

120,000

240,000

80,000

218,000

Flexural Modulus (ASTM D790, psi)

290,000

72,000

145,000

240,000

96,000

220,000

Chemical Resistance

Good

Inert

Inert

Very Good

Inert

Very Good

Melting Temperature (F)

336

621

512

468

581

410

CLTE (ASTM D695, x 10"-5, in/in/F)

6.6

        7.5

7.3

5.6

13

4

      best in class elevated         

                                                                                                  

WHETHER OPTIMIZING YOUR RESIN SELECTION FOR THE APPLICATION OR SIMPLY TRYING TO SECURE THE MATERIALS TO KEEP UP WITH YOUR DEMANDS, CONTACT YOUR LOCAL PORT PLASTICS OFFICE FOR ALL YOUR SEMICONDUCTOR PLASTICS NEEDS!

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ECTFE VS ETFE